2-sec-Butyl-1-(2-hydroxyethyl)-1H-benzimidazole-5-carboxylic acid

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2-sec-Butyl-1-(2-hy­droxy­eth­yl)-1H-benzimidazole-5-carboxylic acid

In the title compound, C(14)H(18)N(2)O(3), the carb-oxy-lic group is tilted by 12.00 (4)° with respect to the mean plane throught the benzimidazole ring system. The alcohol and carboxyl hydroxy groups are involved in intermolecular O-H⋯O and O-H⋯N hydrogen bonds, forming a two-dimensional network extending parallel the ab plane. The network is further stabilized by weak C-H⋯O inter-actions. The...

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Ethyl 1-sec-butyl-2-phenyl-1H-benzimidazole-5-carboxyl­ate

In the title mol-ecule, C(20)H(22)N(2)O(2), the benzimidazole ring system is essentially planar, with a maximum deviation of 0.024 (1) Å. The dihedral angle between the phenyl and benzimidazole ring system is 43.71 (5)°. The atoms of the butyl group are disordered over two sets of sites with occupancies of 0.900 (4) and 0.100 (4). In the crystal structure, mol-ecules are connected by weak inter...

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1-Cyclo­hexyl-2-(3-fur­yl)-1H-benzimidazole-5-carboxylic acid

The asymmetric unit of the title compound, C(18)H(18)N(2)O(3), contains two mol-ecules. The fused rings of both mol-ecules are almost planar, with dihedral angles of 3.1 (1) and 2.8 (2)° between the fused rings. The furan rings are rotated by 43.85 (15) and -21.07 (9)° with respect to the planes of the attached bnzimidazole systems. In the crystal, mol-ecules are linked into infinite chains by ...

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Ethyl 1-sec-butyl-2-(2-hydroxy­phen­yl)-1H-benzimidazole-5-carboxyl­ate 0.25-hydrate

In the title compound, C(20)H(22)N(2)O(3)·0.25H(2)O, the water mol-ecule (occupancy 0.25) is disordered across a crystallographic inversion center. The dihedral angle between the hydroxy-phenyl ring and the benzimidazole ring system is 59.31 (9)°. In the crystal structure, mol-ecules are connected by inter-molecular O-H⋯N and C-H⋯O hydrogen bonds. The crystal structure is further stabilized by ...

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Ethyl 2-(4-bromo­phen­yl)-1-sec-butyl-1H-benzimidazole-5-carboxyl­ate

In the title compound, C(20)H(21)BrN(2)O(2), the bromo-phenyl ring is twisted by 40.13 (8)° from the benzimidazole mean plane and the Br atom deviates by 0.753 (1) Å from that plane. The sec-butyl group is disordered over two conformations in a 0.898 (5):0.102 (5) ratio. In the crystal, mol-ecules related by translation along [[Formula: see text]10] are linked into chains via weak C-H⋯Br hydrog...

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2012

ISSN: 1600-5368

DOI: 10.1107/s1600536812023884